| Name | Party | Ward | End of Term |
|---|
| James Armitage | Conservative and Unionist | Ashover | 2023 |
| Carol Huckerby | Conservative and Unionist | Barlow & Holmesfield | 2023 |
| Peter Elliot | Conservative and Unionist | Brampton & Walton | 2023 |
| Martin Thacker | Conservative and Unionist | Brampton & Walton | 2023 |
| Tracy Reader | Labour Party | Clay Cross North | 2023 |
| Kathleen Rowse | Labour Party | Clay Cross North | 2023 |
| Geoffrey Morley | Labour Party | Clay Cross North | 2023 |
| Margaret Jones | Labour Party | Clay Cross South | 2023 |
| Brian Wright | Labour Party | Clay Cross South | 2023 |
| Anthony Hutchinson | Conservative and Unionist | Coal Aston | 2023 |
| Mark Foster | Conservative and Unionist | Coal Aston | 2023 |
| Philip Wright | Conservative and Unionist | Dronfield North | 2023 |
| Paul Parkin | Conservative and Unionist | Dronfield North | 2023 |
| Angelique Foster-Guembourg | Conservative and Unionist | Dronfield South | 2023 |
| Alan Powell | Conservative and Unionist | Dronfield South | 2023 |
| Kevin Tait | Conservative and Unionist | Dronfield South | 2023 |
| Roger Hall | Conservative and Unionist | Dronfield Woodhouse | 2023 |
| Jeremy Kenyon | Conservative and Unionist | Eckington North | 2023 |
| Oscar Gomez Reaney | Conservative and Unionist | Eckington North | 2023 |
| Jacqueline Ridgway | Labour Party | Eckington South & Renishaw | 2023 |
| Clive Hunt | Labour Party | Eckington South & Renishaw | 2023 |
| Stephen Pickering | Labour Party | Eckington South & Renishaw | 2023 |
| Lilian Deighton | Conservative and Unionist | Gosforth Valley | 2023 |
| Michelle Emmens | Conservative and Unionist | Gosforth Valley | 2023 |
| Richard Welton | Conservative and Unionist | Gosforth Valley | 2023 |
| Lee Hartshorne | Labour Party | Grassmoor | 2023 |
| Elizabeth Hill | Labour Party | Grassmoor | 2023 |
| Suzy Cornwell Ball | Labour Party | Holmewood & Heath | 2023 |
| Lee Stone | Labour Party | Holmewood & Heath | 2023 |
| Nicholas Whitehead | Conservative and Unionist | Killamarsh East | 2023 |
| Kevin Bone | Conservative and Unionist | Killamarsh East | 2023 |
| Stephen Clough | Conservative and Unionist | Killamarsh West | 2023 |
| Maureen Potts | Conservative and Unionist | Killamarsh West | 2023 |
| Patricia Bone | Conservative and Unionist | Killamarsh West | 2023 |
| Jeffrey Lilley | Labour Party | North Wingfield Central | 2023 |
| Nigel Barker | Labour Party | North Wingfield Central | 2023 |
| Jayne Barry | Labour Party | North Wingfield Central | 2023 |
| Patricia Holmes | Labour Party | Pilsley & Morton | 2023 |
| Andrew Cooper | Independent / Other | Pilsley & Morton | 2023 |
| John Funnell | Independent / Other | Pilsley & Morton | 2023 |
| Carolyn Renwick | Conservative and Unionist | Ridgeway & Marsh Lane | 2023 |
| Heather Liggett | Conservative and Unionist | Shirland | 2023 |
| Michael Roe | Conservative and Unionist | Shirland | 2023 |
| Charlotte Cupit | Conservative and Unionist | Shirland | 2023 |
| Joseph Birkin | Labour Party | Sutton | 2023 |
| Patrick Kerry | Labour Party | Sutton | 2023 |
| Pamela Windley | Liberal Democrats | Tupton | 2023 |
| David Hancock | Liberal Democrats | Tupton | 2023 |
| Ross Shipman | Liberal Democrats | Tupton | 2023 |
| Alexander Dale | Conservative and Unionist | Unstone | 2023 |
| Barry Lewis | Conservative and Unionist | Wingerworth | 2023 |
| Diana Ruff | Conservative and Unionist | Wingerworth | 2023 |
| Patricia Antcliff | Conservative and Unionist | Wingerworth | 2023 |
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